Sulfide stress cracking is prevented by minimizing the hardness and strength of. What is the abbreviation for sulfide stress cracking. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. Sulfide stress cracking nicontaining steels transformation start temperature, i. Ssc begins when steels and other susceptible alloys form a reaction with hydrogen sulfide, resulting in atomic hydrogen and metal sulfides as by. It is generally accepted that sulfide stress cracking ssc failures are the result of hydrogen embrittlement. This term should not be confused with stress corrosion cracking scs, since this is anodic in nature. Ssc abbreviation stands for sulfide stress cracking.
Sulfide stress cracking ssc testing southwest research. Ssc testing, proof ring, stress corrosion cracking, sulfide. Standard material requirements materials resistant to. Sulphide stress cracking is prevented by minimising the hardness and strength of the alloys used for wet h2s systems. Sulfide stress cracking of pipelinecase history onepetro. Gas phase water needs to be there as well even in a trace amount. Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc wellhead flow control valve body article pdf available in case studies in engineering failure analysis. Sulfide stress cracking an overview sciencedirect topics. This standard is applicable to the materials andor equipment specified by. Sulfide stress cracking of nickelcontaining lowalloy steels microbially influenced corrosion of steels by oxidative degradation and corrosiveness of biodiesel.
In he as most people use the term, hydrogen is already present in the metal, eg from melting, pickling, etc. Sulphide stress cracking of welded joints in weldable martensitic stainless steels. Hydrogen sulfide is a colorless, very poisonous, flammable gas with the characteristic foul odor of rotten eggs. Sulphide stress corrosion cracking sscc laboratory. Corrosion is a major concern in many industrial installations processing sulfides. Sulfide stress cracking how is sulfide stress cracking. Sulphide stress cracking of joints in martensitic steels twi. In the 19th century, petrus johannes kipp, a dutch pharmacist invented a device that would generate a variety of gases using liquids and solids as regents. The results indicate that flow control valve body failed due to combination of. Sep 29, 2014 link to corrigendum together with my colleagues and good friends dr. Wet hydrogen sulfide h2s cracking inspectioneering. Coilgard inhibitor can be applied as a batch treatment or by placement in the treating fluid. Critical nominal stress and critical stress intensity factors for sulfide stress corrosion cracking of various steels were determined using fatigueprecracked, laboratory, cantilever beam specimens and short lengths of oil field casing and tubing pressured to failure. However, available data remains scarce, in particular, few studies if any have published sufficient details for a full examination of the mechanisms at work.
The major hazards of h 2 s are its ability to cause rapid damage to health or sudden death due to accidental exposure and metal integrity failure due to general corrosion or cracking. Effect of coldwork on sulphide stress cracking resistance twi. Sulfide stress cracking is the worst type of corrosion in the presence of hydrogen sulfide. Sulfide stress cracking is a form of hydrogen embrittlement that occurs in high strength steels and in localized hard zones in weldment of susceptible materials. Sulfide stress cracking ssc occurs at locations where atomic hydrogen is able to diffuse at sites of high internal stress, such as grain boundaries, inclusions and regions of triaxial stress at notches.
Hydrogen sulfide has been studied for hundreds of years. When placed in proximity to tensile stresses, embrittlement and the beginnings of brittle fracture may occur. This standard is applicable to the materials andor equipment specified by the materials standards institutions listed in table 5 or by uivalent standards. Numerous investigations conducted in the past decades outlined its corrosion performance and confirmed its cracking propensity. Ssc of metals exposed to oilfield environments containing h 2 s was recognized as a materials failure problem by 1952. Steels react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. Sulfide stress corrosion cracking of steels corrosion. Tm01772016sg, laboratory testing of metals for resistance to sulfide stress cracking and stress corrosion cracking in h2s environments available for download testing of metals subjected to tensile stresses for resistance to cracking failure in lowph aqueous environments containing hydrogen sulfide h2s. Tcr engineering mumbai corrosion testing, nace, astm.
H 2 s can and does cause metal loss attack which generally tends to be localized due to the tendency for iron sulfide films to be formed on a steel surface ph dependent which breakdown or spall locally leading to pitting. Is sulfide stress cracking an anodic or a cathodic process. Home which alloy is best to resist sulfide stress cracking and stress. Sulfides present in aqueous solution are responsible for stress corrosion cracking scc of steel, and is also known as sulfide stress cracking. Resistance to sulfide stress cracking natural gas and oil inherently contain a certain amount of hydrogen sulphide h 2 s. Wet hydrogen sulfide cracking is a term used for a variety of stress corrosion cracking scc failure modes of carbon steel exposed to aqueous sour refinery environments. Laboratory testing of metals for resistance to sulfide. Sulfide stress cracking ssc is just one of several forms of hydrogen. This nace standard establishes material requirements for resistance to sulfide stress cracking ssc in sour refinery process environments, i. Sulfide stress cracking ssc testing hydrogen sulfide h 2 s is a naturally occurring gas that can be deadly to humans and corrosive to oil and gas equipment, especially in the presence of water.
H 2 s can cause sulfide stress cracking of stainless steels. Sulfide stress cracking ssc vs hydrogen induced cracking hlc. Hydrogen sulfide is known to cause or assist in the mechanism of cracking with many alloy types including low carbon steels, low alloy steels, alloy steels, tool steels, martensitic stainless steels, ferritic stainless steels, austenitic stainless. The evidence sulphide stress corrosion cracking are necessary to evaluate the performance of the materials used in extreme working conditions, such as prolonged exposure to particularly aggressive gases such ash. The iso 151562 standard limits the nickel content in las on the assumption that nickel concentrations above 1wt% negatively impact sulfide stress cracking ssc resistance. This phenomenon is generally termed sulfide stress cracking ssc when operating at room temperature and stress corrosion cracking scc when operating at higher temperatures. The tests are necessary to develop innovative solutions for. In combination with increased temperatures and pressure in environments containing chloride, sulfide stress cracking ssc can occur.
Abstract results of this investigation on the sulfide stress cracking ssc of cast and wrought commercial astm lowalloy steels containing ni showed that the apparent nickel effect is probably an artifact of the divergence of the proportional limit of a steel from its 0. The influence of chemical composition and microstructure of api linepipe steels on hydrogen induced cracking and sulfide stress corrosion cracking. There is a general agreement that plastic strain affects the resistance to sulphide stress cracking, even possibly for low amounts of strain and without significant changes in hardness. Highstrength steels with improved sulfide stress cracking resistance. Sulfide stress corrosion cracking ssc is a form of hydrogen embrittlement cracking which occurs when a susceptible material is exposed to a corrosive environment containing water and h2s at a critical level of applied or residual tensile stress. Evaluation of the seabed temperature corrosion and sulphide. Sulfide stress cracking is also environmentally produced so you have a delay until the sulfide environment causes hydrogen entry into the metal. For this reason, along with toxicity risks of hydrogen sulfide gas, it is essential that water muds be kept entirely free of soluble sulfides and especially hydrogen. Coilgard inhibitor protects against cracking corrosion that can cause catastrophic failures in stressed steels, such as coiled tubing. Sulfide stress cracking is the cracking of a metal under the combined action of tensile stress and corrosion in the presence of water and hydrogen sulfide a form of hydrogen stress cracking. Sulfide stress cracking nace mr01752002, mr0175iso 15156 651 te c h n i c a l new sulfide stress cracking standard for refineries don bush, principal engineer materials, at emerson process management fisher valves, is a member and former chair of a nace task group that has written a document for refinery applications, nace mr0103. The nace mr0175 standards metals for sulfide stress cracking and stress corrosion cracking resistance in sour oilfield environments. Ssc is one of the many environmental cracking mechanisms resulting in pipeline steels exposed to aqueous sour service environments. Sulfide stress cracking is a form of hydrogen embrittlement that occurs in highstrength steels and in localized hard zones in weldment of susceptible.
Which alloy is best to resist sulfide stress cracking and stress corrosion cracking. During investigation many cracks were observed on the inner surface of the valve body grown from the surface pits. In other words, it can support a stress of 80,000 psi with an elongation of less than 0. Stress corrosion cracking, ssc testing, proof ring, tensile test, sulfide stress corrosion cracking, sscc proof ring, sulphide stress corrosion, nace tm0177, corrosion testing equipment, nace tm0177 method a, nace corrosion testing. Sulfide stress corrosion cracking, also known as sulfide stress cracking ssc, is a stress corrosion cracking phenomena that occurs in the presence of hydrogen sulfide. More recently, a number of studies have been concerned with the effect of cold expansion on the resistance to sulphide stress cracking of pipes. This is a complex topic, other factors, such as ph, chloride concentration, and temperature also affect the potential for steel cracking. The national association of corrosion engineers nace test method tm0177 is widely used to qualify metals for resistance to sulfide stress cracking and stress corrosion cracking in h 2 s environments. Typically these conditions occur in oil and gas extraction, predominantly offshore. Sulfide stress cracking oil and gas pipelines wiley online library. Sulfide stress cracking is a function of hydrogen sulfide concentration as low as ppm, hydrogen sulfide partial pressure, stresses, material yield strength, temperature and ph. Feb 04, 2010 hydrogen sulfide principles safety sample. Producing wet sour gas presents some of the toughest technical challenges in the oil and gas business. Some iron sulfides known as pyrophoric iron sulfide are unstable and, when.
Which alloy is for sulfide stress and stress corrosion cracking. Connolly and masakatsu ueda and hisashi amaya and hideki takabe, year20. Pdf sulfide stress corrosion cracking and hydrogen. Sulfide stress cracking is a form of hydrogen embrittlement that occurs in highstrength steels and in localized hard zones in weldment of susceptible materials. In h 2 s containing solutions, hac is referred to as sulphide stress cracking ssc, an acronym traditionally used in the international standards dedicated to the oil and gas industry. Hydrogen sulfide h 2 s is a naturally occurring gas that can be deadly to humans and corrosive to oil and gas equipment, especially in the presence of water. Sulfide stress cracking mostly occurs in very highly acidic environments. Dec 21, 2017 in other words, it can support a stress of 80,000 psi with an elongation of less than 0. In oil and gas production systems containing hydrogen sulphide h 2 s, however, this material is highly susceptible to sulphide stress cracking ssc. Nace mr0175 and mr0103 standards metals for sulfide stress. S hydrogen sulfide, that is found especially in the extractive industry.
Hydrogen sulfide hsub 2s has long been associated with the cause of corrosion damage and sulfide stress cracking ssc in high strength steels and high hardness weldments used in oil and gas production, petroleum refining, and petrochemicalchemical processing. Effect of coldwork on sulphide stress cracking resistance. Basics of sulfide stress cracking ssc and stress corrosion cracking scc ssc and scc are cracking processes that develop in the presence of water, corrosion and surface tensile stress. Ian sutton, in plant design and operations second edition, 2017. Sulfide stress cracking ssc of high strength, low alloy steel is a phenomenon of particular concern to the oil and gas industry 3. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking. Sulfide stress cracking is also called hydrogen sulfide cracking, sulfide cracking, sulfide corrosion cracking and sulfide stress corrosion cracking. Sulfide stress cracking of nickelcontaining lowalloy. As we know that both form of cracking are due to the absorption of atomic hydrogen that is produced by. Which alloy is for sulfide stress and stress corrosion. Sulfide stress cracking of nickel steels corrosion. Sulfide stress cracking of nickelcontaining lowalloy steels. Sulfide stress cracking of highstrength steels in laboratory.
Sulphide stress cracking of 174 ph for applications in. Typical standards are efc 16 2009, nace tm0284 2011 for hic resistance and nace tm0177 2005 for ssc resistance. Sulfide stress cracking ssc vs hydrogen induced cracking hlc posted in refining, hydrocarbons, oil, and gas. Materials selection properties the levels of strength in agehardened materials becoming increasingly important, particularly for offshore applications that are exploiting highpressure deep well reserves, where weight considerations can affect the economic viability of a project. Corrosionpedia what is sulfide stress cracking ssc. Sulfide stress cracking nace mr01752002, mr0175iso 15156.
Sulfide stress cracking is a form of hydrogen embrittlement that occurs in highstrength steels and in localized hard zones in weldment of susceptible materials when the environment contains wet h 2 s. Factors affecting the sulfide stress cracking performance. Dec 19, 2019 sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc. However, the evidence heretofore has been mostly circumstantial. Element performs sulfide stress cracking ssc testing of metals subject to cracking under the combined action of tensile stress and corrosion in the presence of water and h2s, in compliance with nace tm0177 iso 15156 standards. It is intended to be used by refineries, equipment manufacturers, engineering contractors, and. Hydrogen sulfide is known to cause or assist in the mechanism of cracking with many alloy types including low carbon steels, low alloy steels, alloy steels, tool steels, martensitic stainless steels, ferritic stainless steels, austenitic stainless steels, duplex stainless steels, nickelcopper alloys, and nickelbase alloys. The purpose of this paper is to provide the experimental evidence which establishes the causality of hydrogen and the contributory roles of h 2 s and anodic dissolution. Evaluation of the seabed temperature corrosion and.
This standard presents metallic material requirements for resistance to sulfide stress cracking ssc for petroleum production, drilling, gathering and flowline equipment, and field processing facilities to be used in hydrogen sulfide h2sbearing hydrocarbon service. This standard addresses the testing of metals for resistance to cracking failure under the combined action of tensile stress and corrosion in aqueous environments containing hydrogen sulfide h 2 s. Sulphide stress corrosion cracking tests pontlab srl. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. Typical standards are efc 16 2009, nace tm0284 2011 for hic resistance. Sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. Sulfide stress cracking nace mr01752002, mr0175iso. Sulfide stress cracking ssc vs hydrogen induced cracking. It is a progressive type of failure that produces cracking at stress levels that are well below the materials tensile strength. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. Sulfide stress cracking oil and gas pipelines wiley. The role of hydrogen in sulfide stress cracking of low alloy. The letter in conjunction with the number designates parameters such as the maximum yield strength and the minimum ultimate strength which for l80 pipe are 95,000 psi.
1157 210 623 163 861 1608 1108 973 981 1068 1381 1147 137 571 1176 1264 485 308 1667 400 1019 1494 748 315 1092 1542 1154 1333 578 1454 451 1459 1081 128 472 788 789 427